Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321766182
Author: Thomas Engel, Philip Reid
Publisher: Prentice Hall
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Chapter 1, Problem 1.12NP
A rigid vessel of volume
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The following equations of state are occasionally used for approximate calculations on gases: (gas A) pVm = RT(1 + b/Vm), (gas B) p(Vm − b) = RT. Assuming that there were gases that actually obeyed these equations of state, would it be possible to liquefy either gas A or B? Would they have a critical temperature? Explain your answer.
(a) A tank contains one mole of oxygen gas at a pressure of 6.30 atm and a temperature of 29.5°C. The tank (which has a fixed volume) is heated until the pressure inside triples. What is the final temperature of the gas?
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A 0.526 g sample of a metal, M, reacts completely with sulfuric acid according to
M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g)
A volume of 243 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. Calculate the molar mass of the metal.
Chapter 1 Solutions
Thermodynamics, Statistical Thermodynamics, & Kinetics
Ch. 1 - Real walls are never totally adiabatic. Use your...Ch. 1 - The parameter a in the van der Waals equation is...Ch. 1 - Give an example based on molecule—molecule...Ch. 1 - Prob. 1.4CPCh. 1 - Prob. 1.5CPCh. 1 - The location of the boundary between the system...Ch. 1 - Prob. 1.7CPCh. 1 - At sufficiently high temperatures, the van der...Ch. 1 - Prob. 1.9CPCh. 1 - Prob. 1.10CP
Ch. 1 - Prob. 1.11CPCh. 1 - Prob. 1.12CPCh. 1 - Prob. 1.13CPCh. 1 - The mass of a He atom is less than that of an Ar...Ch. 1 - Prob. 1.15CPCh. 1 - Prob. 1.1NPCh. 1 - A compressed cylinder of gas contains 2.74103g of...Ch. 1 - Calculate the pressure exerted by Ar for a molar...Ch. 1 - A sample of propane C3H8 is placed in a closed...Ch. 1 - A gas sample is known to be a mixture of ethane...Ch. 1 - One liter of fully oxygenated blood can carry 0.18...Ch. 1 - Yeast and other organisms can convert glucose...Ch. 1 - A vessel contains 1.15 g liq H2O in equilibrium...Ch. 1 - Consider a 31.0 L sample of moist air at 60.C and...Ch. 1 - Prob. 1.10NPCh. 1 - Prob. 1.11NPCh. 1 - A rigid vessel of volume 0.400m3 containing H2 at...Ch. 1 - A mixture of oxygen and hydrogen is analyzed by...Ch. 1 - An athlete at high performance inhales 3.75L of...Ch. 1 - Devise a temperature scale, abbreviated G, for...Ch. 1 - Aerobic cells metabolize glucose in the...Ch. 1 - Prob. 1.17NPCh. 1 - A mixture of 2.10103g of O2, 3.88103mol of N2, and...Ch. 1 - Prob. 1.19NPCh. 1 - Prob. 1.20NPCh. 1 - An initial step in the biosynthesis of glucose...Ch. 1 - Prob. 1.22NPCh. 1 - Assume that air has a mean molar mass of 28.9gmol1...Ch. 1 - When Julius Caesar expired, his last exhalation...Ch. 1 - Calculate the number of molecules per m3 in an...Ch. 1 - Prob. 1.26NPCh. 1 - A mixture of H2 and NH3 has a volume of 139.0cm3...Ch. 1 - A sealed flask with a capacity of 1.22dm3 contains...Ch. 1 - A balloon filled with 11.50 L of Ar at 18.7C and 1...Ch. 1 - Carbon monoxide competes with oxygen for binding...Ch. 1 - The total pressure of a mixture of oxygen and...Ch. 1 - Suppose that you measured the product PV of 1 mol...Ch. 1 - Liquid N2 has a density of 875.4kgm3 at its normal...Ch. 1 - Calculate the volume of all gases evolved by the...Ch. 1 - Prob. 1.35NPCh. 1 - A glass bulb of volume 0.198 L contains 0.457 g of...Ch. 1 - Prob. 1.37NPCh. 1 - Prob. 1.38NPCh. 1 - Many processes such as the fabrication of...Ch. 1 - Rewrite the van der Waals equation using the molar...
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- What is the temperature in K of 0.500 mole of neon in a 2.00L vessel at 4.32 bar? R = 0.08314 L· bar/mol·K.arrow_forwardA 0.244 g sample of a metal, M, reacts completely with sulfuric acid according to M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g) A volume of 255 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. The vapor pressure of water at 25 °C is 23.8 Torr. Calculate the molar mass of the metal.arrow_forwardA 1.00 LL flask is filled with 1.45 gg of argon at 25 ∘C∘C. A sample of ethane vapor is added to the same flask until the total pressure is 1.400 atm. What is the partial pressure of ethane, PethanePethaneP_ethane, in the flask? Express your answer to three significant figures and include the appropriate units.arrow_forward
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