See attached picture. TABLE 13.3 Correlation of H Chemical Shift with EnvironmentChemicalshift (5)Chemicalshift (5)Type of hydrogenType of hydrogenReference(CH) SiSaturatedprimary-CHAlkyl halideX- CI, Br, I0.7-1.32.5-4.0-CH-Saturatedsecondary1.2-1.6Alcohol2.5-5.0(Variable)HAlcohol,ether3.3-4.5Saturatedtertiary1.4-1.8H.H.-H-Vinylic4.5-6.5Allylic1.6-2.2AromaticAr-H6.5-8.0Methylketone2.0-2.4Aldehyde9.7-10.0CHH.AromaticAr-CH2.4-2.7methylCarboxylicacid11.0-12.0Alkynyl-C=C-H2.5-3.0©2004 Thomson - Brooks/Coleo=o= 2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMRbelow and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of thatmajor product can be made in the reaction, provide only one of them.a)HBrbenzoyl peroxidemolecule 26H3H3H2H2H1H8.3PPMb) What would you expect the optical rotation of themajor product mixture formed in the reaction frommolecule 2 to be? (circle the correct answer)A Positive orNegative ValueCannot0°Determine

Alkene reacts with HBr in presence of peroxide to form alkyl bromide. In this reaction, the HBr…

2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMR below and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of that major product can be made in the reaction, provide only one of them. a) HBr benzoyl peroxide molecule 2 6H 3H 3H 2H 2H 1H PPM b) What would you expect the optical rotation of the major product mixture formed in the reaction from molecule 2 to be? (cirele the correct answer) A Positive or Negative Value Cannot 0° Determine

2) When molecule 2 is treated with HBr and peroxide one major product is formed. Based off of the NMR below and the reaction conditions, provide the major product in the box below. If multiple stereoisomers of that major product can be made in the reaction, provide only one of them. a) HBr benzoyl peroxide molecule 2 6H 3H 3H 2H 2H 1H PPM b) What would you expect the optical rotation of the major product mixture formed in the reaction from molecule 2 to be? (cirele the correct answer) A Positive or Negative Value Cannot 0° Determine

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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3) Consider the chemical transformation below. moth a) Predict the major product of the reaction by drawing it in the space above. b) Provide an explanation for how mass-spectroscopy could be used to confirm the substrate was successfully transformed into the product. RCO3H c) Provide at least one piece of ¹H NMR evidence and one piece of 13C NMR evidence that you could use to confirm the substrate was successfully transformed into the product.
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