Evib = @. + @.ye v+• +... %3D Molecule u (amu) k (Nm-') we(cm-1) Wxe (cm-1) wYe (cm¬1) 'H 1271 1.00 310 2309.60 39.36 -0.09 2H 1°F 1.82 960 2998.19 45.76 12C 160 6.86 1900 2169.82 13.29 0.01 14N !ªN 7.00 2290 2358.07 14.19 -0.01 14N 160+ 7.47 2490 2377.48 16.45 14N 160 7.47 1600 1904.41 14.19 0.02 14N 160- 7.47 830 1372 160 l60 8.00 1180 1580.36 12.07 0.05 19F 1ºF 9.50 440 891.2 35C1 5CI 17.48 320 560.50 2.90 0.02
Evib = @. + @.ye v+• +... %3D Molecule u (amu) k (Nm-') we(cm-1) Wxe (cm-1) wYe (cm¬1) 'H 1271 1.00 310 2309.60 39.36 -0.09 2H 1°F 1.82 960 2998.19 45.76 12C 160 6.86 1900 2169.82 13.29 0.01 14N !ªN 7.00 2290 2358.07 14.19 -0.01 14N 160+ 7.47 2490 2377.48 16.45 14N 160 7.47 1600 1904.41 14.19 0.02 14N 160- 7.47 830 1372 160 l60 8.00 1180 1580.36 12.07 0.05 19F 1ºF 9.50 440 891.2 35C1 5CI 17.48 320 560.50 2.90 0.02
Chemistry for Engineering Students
3rd Edition
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter5: Gases
Section: Chapter Questions
Problem 5.23PAE
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Calculate the vibrational energy of the v = 2 state of 1H127 I relative to the ground state, including the anharmonic corrections.
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