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Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter13: Acids And Bases

Section: Chapter Questions

Problem 170CP

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Question

3. A 6.8 M of HNO3 is added to water at 25°C
a. Should this be process be shown with an equilibrium arrow or a one direction arrow? Why?
b. Write the balanced net ionic equation including state symbols
c. Identify the acid, base, conjugate acid and conjugate base in the equation
d. Calculate the pH of the solution
e. Calculate the pOH of solution

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Why have chemists not tabulated the fraction ionized for different acids? Such a table would make problems such as calculating the pH of an acid solution quite simple.
Find [H+] and the pH of the following solutions. (a) A 456-mL sample of a 12.0% (by mass) solution of HNO3(d=1.00g/mL). What is the pH of 10.0 mL of the same sample? (b) A solution made up of 1.0 g of HCI dissolved in enough water to make 1.28 L of solution. What is the pH of the solution? If the same mass of HCI is dissolved in enough water to make 128 mL of solution, what would the pH be?
Consider two weak acids, HA (MM=138g/mol)and HB (MM=72.0g/mol). A solution consisting of 11.0 g of HA in 745 mL has the same pH as a solution made up of 5.00 g of HB in 525 mL. Which of the two acids is stronger? Justify your answer by an appropriate calculation.
Novocaine, C13H21O2N2Cl, is the salt of the base procaine and hydrochloric acid. The ionization constant for procaine is 7106. 15 a solution of novocaine acidic or basic? What are [H3O+], [OH-], and pH of a 2.0% solution by mass of novocaine, assuming that the density of the solution is 1.0 g/mL.
A student prepares 455 mL of a KOH solution, but neglects to write down the mass of KOH added. His TA suggests that he take the pH of the solution. The pH is 13.33. How many grams of KOH were added?
. Consider 0.25 M solutions of the following salts: NaCl. RbOC1, KI, Ba(ClO4),, and NH4NO3. For each salt, indicate whether the solution is acidic, basic, or neutral.
. Using Fig. 16.3, list the approximate pH value of live “everyday” solutions. How do the familiar properties (such as the sour taste for acids) of these solutions correspond to their indicated pH?
Find [OH+], [OH-] and the pH of the following solutions. (a) 30.0 mL of a 0.216 M solution of HCI diluted with enough water to make 125 mL of solution. (b) A solution made by dissolving 275 mL of HBr gas at 25C and 1.00 atm in enough water to make 475 mL of solution. Assume that all the HBr dissolves in water.

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