The NMR spectrum contains a fairly complicated set of signals for the 'H-atoms labeled Ha shown below. Complete the following exercises to address the complexity. O Ha Ha He H. He

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter13: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 13.28P
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Biginelli product to the left

 

The actual Hd atoms in the Biginelli product have slightly different chemical and physical properties. As a result, they create two separate 1H-NMR signals and display a two-bond coupling (2 JHH). Identify the cause of these two Hd atoms having slightly different chemical and physical properties by making explicit reference to the Biginelli product.

Biginelli product to the left.

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The NMR spectrum contains a fairly complicated set of signals for the 'H-atoms labeled Ha
shown below. Complete the following exercises to address the complexity.
о на На
He
Transcribed Image Text:The NMR spectrum contains a fairly complicated set of signals for the 'H-atoms labeled Ha shown below. Complete the following exercises to address the complexity. о на На He
(Hn) NO2
(Н)
>(Hg)
(H)
(Hi)
Ha-N
(На
(Hal (He)
N.
Me
Н, (Н.)
Transcribed Image Text:(Hn) NO2 (Н) >(Hg) (H) (Hi) Ha-N (На (Hal (He) N. Me Н, (Н.)
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