The intramolecular Aldol condensation of 2,6-heptanedione with base may produces two possible B-hydroxyl ketones as shown in the following reaction pathway. CH, (1) OH CH, (A) 3-Methyl-2-cyclohexenone CH, CH, (2) Он CH, 2,6-Heptanedione (B) Methyl(2-methyl-1-cyclobutenyl)ketone (i) Write detailed mechanisms for both the reactions (1) and (2).
The intramolecular Aldol condensation of 2,6-heptanedione with base may produces two possible B-hydroxyl ketones as shown in the following reaction pathway. CH, (1) OH CH, (A) 3-Methyl-2-cyclohexenone CH, CH, (2) Он CH, 2,6-Heptanedione (B) Methyl(2-methyl-1-cyclobutenyl)ketone (i) Write detailed mechanisms for both the reactions (1) and (2).
Chapter23: Carbonyl Condensation Reactions
Section23.3: Dehydration Of Aldol Products: Synthesis Of Enones
Problem 4P
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![The intramolecular Aldol condensation of 2,6-heptanedione with base may produces two possible
B-hydroxyl ketones as shown in the following reaction pathway.
CH,
(1) OH
CH,
(A) 3-Methyl-2-cyclohexenone
CH,
CH,
(2) Он
CH,
2,6-Heptanedione
(B) Methyl(2-methyl-1-cyclobutenyl)ketone
(i)
Write detailed mechanisms for both the reactions (1) and (2).](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F94bf5148-2736-4275-bd92-ea3e4c78a0da%2F5bb9aa52-8b7f-41d0-af7a-3555e3f67968%2Fqxf4ezs_processed.png&w=3840&q=75)
Transcribed Image Text:The intramolecular Aldol condensation of 2,6-heptanedione with base may produces two possible
B-hydroxyl ketones as shown in the following reaction pathway.
CH,
(1) OH
CH,
(A) 3-Methyl-2-cyclohexenone
CH,
CH,
(2) Он
CH,
2,6-Heptanedione
(B) Methyl(2-methyl-1-cyclobutenyl)ketone
(i)
Write detailed mechanisms for both the reactions (1) and (2).
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