Show how you can carry out the following transformations with the limitations given below and any readily available (i. e. existing!) reagents. If more than one step is required, give reagents and product(s) for each step. Show structures for all the compounds. Reaction mechanisms NOT required Include a protection group on benzene. OY NH₂ NO2
Show how you can carry out the following transformations with the limitations given below and any readily available (i. e. existing!) reagents. If more than one step is required, give reagents and product(s) for each step. Show structures for all the compounds. Reaction mechanisms NOT required Include a protection group on benzene. OY NH₂ NO2
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...
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Step 1
There are 2 steps in following conversion -
1) First step is nitration . Nitration in presence of HNO3/ H2SO4 take place and two products will form . Othro nitroacetanilide and para nitroacetaanilide . Para product will be major product while ortho is minor product.
2) second step involve acid hydrolysis which converts o - nitroacetanilide into o- Nitroaniline .
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