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Prepare a properly scaled and labeled LCAO correlation diagram for HCI, notating atomic orbital energies using the table of orbital energies available in the resource section of the Day 28 Canvas daily page. (a) Sketch pictures of the highest occupied and the lowest unoccupied molecular orbitals (HOMO and LUMO, respectively) for HCl, using appropriate labels/shading to indicate where the wave function changes phase (b) At right is the photoelectron spectrum for HCI, with two features highlighted in color; assign these features to the MOs from which the ejected electrons originate. (c) Would the energy required to excite an electron from the HOMO to the LUMO of HCI equal the molecule's bond dissociation energy? Why or why not? 14 16 ionization energy/eV 18

Prepare a properly scaled and labeled LCAO correlation diagram for HCI, notating atomic orbital energies using the table of orbital energies available in the resource section of the Day 28 Canvas daily page. (a) Sketch pictures of the highest occupied and the lowest unoccupied molecular orbitals (HOMO and LUMO, respectively) for HCl, using appropriate labels/shading to indicate where the wave function changes phase (b) At right is the photoelectron spectrum for HCI, with two features highlighted in color; assign these features to the MOs from which the ejected electrons originate. (c) Would the energy required to excite an electron from the HOMO to the LUMO of HCI equal the molecule's bond dissociation energy? Why or why not? 14 16 ionization energy/eV 18

Materials Science And Engineering Properties
Materials Science And Engineering Properties
1st Edition
ISBN:9781111988609
Author:Charles Gilmore
Publisher:Charles Gilmore
Chapter15: Experimental Methods
Section: Chapter Questions
Problem 7ETSQ
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Prepare a properly scaled and labeled LCAO correlation diagram for HCI, notating atomic orbital energies using the table of orbital energies available in the resource section of the Day 28 Canvas daily page. (a) Sketch pictures of the highest occupied and the lowest unoccupied molecular orbitals (HOMO and LUMO, respectively) for HCl, using appropriate labels/shading to indicate where the wave function changes phase (b) At right is the photoelectron spectrum for HCI, with two features highlighted in color; assign these features to the MOs from which the ejected electrons originate. (c) Would the energy required to excite an electron from the HOMO to the LUMO of HCI equal the molecule's bond dissociation energy? Why or why not? 14 16 ionization energy/eV 18
Transcribed Image Text:Prepare a properly scaled and labeled LCAO correlation diagram for HCI, notating atomic orbital energies using the table of orbital energies available in the resource section of the Day 28 Canvas daily page. (a) Sketch pictures of the highest occupied and the lowest unoccupied molecular orbitals (HOMO and LUMO, respectively) for HCl, using appropriate labels/shading to indicate where the wave function changes phase (b) At right is the photoelectron spectrum for HCI, with two features highlighted in color; assign these features to the MOs from which the ejected electrons originate. (c) Would the energy required to excite an electron from the HOMO to the LUMO of HCI equal the molecule's bond dissociation energy? Why or why not? 14 16 ionization energy/eV 18
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