halogenation

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
Which product is the major and minor in a halogenation reaction with cl2
"For each halogen, reactivities with four types of alkane C-H bonds are normalized to the reactivity of th
2-151 O
(tert-Butyl bromidej
90%
:
Less (primary)
0.06%mi
10%
Expected (statistical) ratio
C-H bond reactivity
Experimental ratio
More (tertiary)
99.94%
In Summary Increased reactivity goes hand in hand with reduced selectivity in radied.
stitution reactions. Fluorine and chlorine, the more reactive halogens, discriminate ba
the various types of C-H bonds much less than does the less reactive bromine (Table 3.
Relative Reactivities of the Four Types of Alkane C-H Bonds
in Halogenations
Table 3-6
F•
e Cl.
(25°C, gas)
C-H bond
Br
(150°C, g
(25°C, gas)
CH3-H
RCH-H"
R,CH-H
R;C-H
0.5
1
0.004
0.002
1.2
1
1
1.4
4
80
primary C-H bond.
1700
Transcribed Image Text:"For each halogen, reactivities with four types of alkane C-H bonds are normalized to the reactivity of th 2-151 O (tert-Butyl bromidej 90% : Less (primary) 0.06%mi 10% Expected (statistical) ratio C-H bond reactivity Experimental ratio More (tertiary) 99.94% In Summary Increased reactivity goes hand in hand with reduced selectivity in radied. stitution reactions. Fluorine and chlorine, the more reactive halogens, discriminate ba the various types of C-H bonds much less than does the less reactive bromine (Table 3. Relative Reactivities of the Four Types of Alkane C-H Bonds in Halogenations Table 3-6 F• e Cl. (25°C, gas) C-H bond Br (150°C, g (25°C, gas) CH3-H RCH-H" R,CH-H R;C-H 0.5 1 0.004 0.002 1.2 1 1 1.4 4 80 primary C-H bond. 1700
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Ethers
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY