Given the following thermodynamic data, calculate the lattice energy of CaBr2 (s). Term Value (kJ/mol) AĦ[CaBr2 (s)] -675 AH[Ca(g)] 178 AĘ Br(g)] 112 n(Ca) 590. I2 (Ca) 1145 EA(Br) -325 Express your answer to four significant figures, and include the appropriate units.

Chemistry: The Molecular Science
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Chapter6: Covalent Bonding
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Problem 98QRT
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Please answer question 17 part A and B

By convention, the lattice energy is the energy
required to form one mole of a solid ionic crystalline
lattice from its gaseous ions. Since we cannot
directly measure lattice energies, we generally use
the Born-Haber cycle to calculate the lattice energy
I Review I Con
Part A
from other measurable quantities. For instance, the
Born-Haber cycle of sodium chloride is shown
below.
Rank the following ionic compounds by the magnitude of their lattice energy.
(Figure 1)
Rank from highest to lowest magnitude of lattice energy.
In this cycle, the lattice energy is calculated using
the following parameters. The associated reaction
for each is shown in Figure 1.
• View Available Hint(s)
AĦ[NaCl(s)], enthalpy of
Help
Reset
formation of NaCI
AH Cl(g)], enthalpy of formation
of gaseous CI
AH Na(g)], enthalpy of formation
of gaseous Na
I1 (Na), first ionization energy of Na
EA(CI)], electron affinity of Cl
Beo
Na20
LiCl
MgO
Na,S
Figure
1 of 1
Na*(g) + e¯+ CI(g)
Highest magnitude
Lowest magnitude
1,(Na)↑
Na(g)
T
ci (g) + Na*(g)
EA(CI)
AH [Na(g)]¶ Na(s) + CI(g)
↑aH¡[CI(g)]
Na(s) + ¿Cl2(g)
AH¡[NaCI(s)]|
NaCI(s)
The correct ranking cannot be determined.
Born-Haber Cycle
Lattice energy
Transcribed Image Text:By convention, the lattice energy is the energy required to form one mole of a solid ionic crystalline lattice from its gaseous ions. Since we cannot directly measure lattice energies, we generally use the Born-Haber cycle to calculate the lattice energy I Review I Con Part A from other measurable quantities. For instance, the Born-Haber cycle of sodium chloride is shown below. Rank the following ionic compounds by the magnitude of their lattice energy. (Figure 1) Rank from highest to lowest magnitude of lattice energy. In this cycle, the lattice energy is calculated using the following parameters. The associated reaction for each is shown in Figure 1. • View Available Hint(s) AĦ[NaCl(s)], enthalpy of Help Reset formation of NaCI AH Cl(g)], enthalpy of formation of gaseous CI AH Na(g)], enthalpy of formation of gaseous Na I1 (Na), first ionization energy of Na EA(CI)], electron affinity of Cl Beo Na20 LiCl MgO Na,S Figure 1 of 1 Na*(g) + e¯+ CI(g) Highest magnitude Lowest magnitude 1,(Na)↑ Na(g) T ci (g) + Na*(g) EA(CI) AH [Na(g)]¶ Na(s) + CI(g) ↑aH¡[CI(g)] Na(s) + ¿Cl2(g) AH¡[NaCI(s)]| NaCI(s) The correct ranking cannot be determined. Born-Haber Cycle Lattice energy
Part B
Given the following thermodynamic data, calculate the lattice energy of CaBr2 (s).
Term
Value (kJ/mol)
AĦ(CaBr2 (s)]
-675
AĘ[Ca(g)]
178
AĦĘB1(g)]
112
(Ca)
590.
I2 (Ca)
1145
EA(Br)
-325
Express your answer to four significant figures, and include the appropriate units.
• View Available Hint(s)
HẢ
ΔΗatt
Value
Units
%3D
Transcribed Image Text:Part B Given the following thermodynamic data, calculate the lattice energy of CaBr2 (s). Term Value (kJ/mol) AĦ(CaBr2 (s)] -675 AĘ[Ca(g)] 178 AĦĘB1(g)] 112 (Ca) 590. I2 (Ca) 1145 EA(Br) -325 Express your answer to four significant figures, and include the appropriate units. • View Available Hint(s) HẢ ΔΗatt Value Units %3D
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