For the gas-phase reaction A + A → A2, the experimental rate constant, kr, has been fitted to the Arrhenius equation with a frequency factor A = 4.07 × 105 dm3 mol−1 s−1 at 300 K and an activation energy of 65.4 kJ mol−1. Calculate Δ‡S, Δ‡H, Δ‡U, and Δ‡G for the reaction.

For the gas-phase reaction A + A → A2, the experimental rate constant, kr, has been fitted to the Arrhenius equation with a frequency factor A = 4.07 × 105 dm3 mol−1 s−1 at 300 K and an activation energy of 65.4 kJ mol−1. Calculate Δ‡S, Δ‡H, Δ‡U, and Δ‡G for the reaction.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter20: Kinetics

Section: Chapter Questions

Problem 20.38E: List at least four experimentally determined parameters that you, an experimenter, can define when...

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Question

For the gas-phase reaction A + A → A₂, the experimental rate constant, kr, has been fitted to the Arrhenius equation with a frequency factor A = 4.07 × 10⁵ dm³ mol⁻¹ s⁻¹ at 300 K and an activation energy of 65.4 kJ mol⁻¹. Calculate Δ^‡S, Δ^‡H, Δ^‡U, and Δ^‡G for the reaction.

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