Figure 7 of Conrad et al. (1999) shows the variation in C-isotopic composition of CO₂ as a function of the concentration of methane measured in the soil and aquifers of a site contaminated in the residues of aviation fuels. Explain briefly the aim of these particular measurements made to the environmental study. Also explain briefly why there is a difference in isotopic composition of CO₂ obtained via aerobic degradation and methanogenic degradation of AVGAS (fuel residues as contaminants) and the linear "mixing relationship" noted in Figure 7. CH₂ 35 30- 25 20 methane oxidation methanogenic degradation of AVGAS

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter30: Capillary Electrophoresis, Electrochromatography, And Field-flow Fractionation
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Problem 30.9QAP
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Figure 7 of Conrad et al. (1999) shows the variation in C-isotopic composition of
CO2 as a function of the concentration of methane measured in the soil and
aquifers of a site contaminated in the residues of aviation fuels. Explain briefly
the aim of these particular measurements made to the environmental study. Also
explain briefly why there is a difference in isotopic composition of CO2 obtained
via aerobic degradation and methanogenic degradation of AVGAS (fuel residues
as contaminants) and the linear "mixing relationship" noted in Figure 7.
35
30
methane oxidation
methanogenic
degradation
of AVGAS
25 -
20
15
Sampling
Locations
10
aerobie
degradation of
AVGAS
A 12
• 13
5
6.
14
O 20
O 21
9
O 10
-30
-25
-20
-15
-10
-5
8®C (%c) of CO,
Fig. 7. Plot of %CH4 vs the 8'³C values of CO2 by sample location for all samples containing CH4 from the study site. The dashed
line is a best fit line through the data. Also shown are the approximate fields that would be expected for methanogenic and aerobic
degradation of AVGAS, and the trend that would be expected for significant levels of methane oxidation.
% CH,
Transcribed Image Text:Figure 7 of Conrad et al. (1999) shows the variation in C-isotopic composition of CO2 as a function of the concentration of methane measured in the soil and aquifers of a site contaminated in the residues of aviation fuels. Explain briefly the aim of these particular measurements made to the environmental study. Also explain briefly why there is a difference in isotopic composition of CO2 obtained via aerobic degradation and methanogenic degradation of AVGAS (fuel residues as contaminants) and the linear "mixing relationship" noted in Figure 7. 35 30 methane oxidation methanogenic degradation of AVGAS 25 - 20 15 Sampling Locations 10 aerobie degradation of AVGAS A 12 • 13 5 6. 14 O 20 O 21 9 O 10 -30 -25 -20 -15 -10 -5 8®C (%c) of CO, Fig. 7. Plot of %CH4 vs the 8'³C values of CO2 by sample location for all samples containing CH4 from the study site. The dashed line is a best fit line through the data. Also shown are the approximate fields that would be expected for methanogenic and aerobic degradation of AVGAS, and the trend that would be expected for significant levels of methane oxidation. % CH,
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