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- 6-40 Give the substitution products expected from solvolysis of each compound by heating in ethanol. (a) (b) (c) Br (d) Br CI CH3 BrComplete the following reactions by identifying the major product(s) or the missing reaction conditions. No mechanism is needed. a) PCC OH HO CH₂Cl2 no necessary reagents for this equilibrium b) c) Hg(OAc)2 H₂SO4, H₂OMechanism: A reaction mechanism for the following reaction is shown below. H+ CEN CEN: N-H || -C-OH H₂O, H* Step 1 wand woled mot ozsm E Step 3 N-H C-OH C=N-H Step2 C=N-H H-O-H H₂O motno vgiene fesrigid onlt to smotnos -C=N-H a) The overall reaction is an example of b) Step 1 is c) Step 3 is d) Draw in the curved arrows for each step. e) Identify the nucleophiles and electrophiles where appropriate. f) Fill in the reaction energy diagram. H₂O: rate determining step to noipojovo hamwell sit 5(emise erit voittons 10) vanas mi sdgin al rainW di of E^ reaction progress →
- 8-8 Identify the major product(s) of the following reactions. Include stereochemistry. (a) (b) (c) Br NaOEt NaOEt NaOEtThe following reaction can be carried out in two steps. Choose the correct reagents i) and ii) to perform the following reaction. CN Oi) H₂O, acid catalyst; ii) CN Oi) HBr; ii) CNT Oi) CN; ii) H₂O, acid catalyst i) CN; ii) heat i) Br₂; ii) CN .Drawing Reaction Mechanism Arrows:
- reactions. Provide the curved Predict the products of the following arrows to explain how the product is forned through the indicated mechanism. (a) S,2 reaction Br NaSH + (b) S,1 reaction NH3 Br (С) Е2 гeaction Br NaOHFor the reaction below, draw a step-by-Step mechanism (ar rOus men drawa reaction Coordinate diagram as well as mě Struckare of she ransHlon state m for the reacon mechanism for the first Step in the mechanism consist ent with me Hammond Postulate : Но -Br CH gCH2OH + HBr7-57 Predict the major product in each of the following reactions: (a) CH3 H20 CH3CH,CH=ĊCH,CH3 ? H2SO4 (Addition of H20 occurs.) (b) LCH2CH3 HBr ? (c) CH3 HBr ? 2 HCI (d) H2C=CHCH,CH,CH2CH=CH2
- 7A Write the possible products of the following reactions, the mechanism by which they were formed. mentioning Br CH3OH CH3ONaProvide the structure(s) of the expected major organic product of the reaction shown. 1) Disiamylborane 2) H₂O₂, NaOH OI O II ||| O IV OV CH3CH₂C(CH3)2C=CH OH OH xx xo IVConsider the reaction below. If the concentration of the nucleophile is doubled, the rate of the reaction will If the concentration of the alkyl halide is doubled, the rate of the reaction will H₂O x CI OH (c) double, not change (d) triple, triple (a) not change, double(b) double, double (e) not change, not change