Consider the constitutional isomers depicted below. One of these has a strong IR absorption peak at 1700 cm³¹. The base peak in the mass spectrum occurs at m/z = 105 as the result of an a- cleavage. A significant peak at m/z = 120 results from a McLafferty rearrangement. Which structure is most consistent with this data? on ol IV A) I B) II C) III D) IV

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
Section12.SE: Something Extra
Problem 15AP: Write molecular formulas for compounds that show the following molecular ions in their...
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Consider the constitutional isomers depicted below. One of these has a strong IR
absorption peak at 1700 cm³¹.
The base peak in the mass spectrum occurs at m/z = 105 as the result of an a-
cleavage. A significant peak at m/z = 120 results from a McLafferty
rearrangement.
Which structure is most consistent with this data?
IV
A) I
B) II
C) III
D) IV
Transcribed Image Text:||| Consider the constitutional isomers depicted below. One of these has a strong IR absorption peak at 1700 cm³¹. The base peak in the mass spectrum occurs at m/z = 105 as the result of an a- cleavage. A significant peak at m/z = 120 results from a McLafferty rearrangement. Which structure is most consistent with this data? IV A) I B) II C) III D) IV
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