6-Consider the first ionization of sulfurous acid: H2SO3(aq) → H*(aq) + HSO3¨(aq) Certain related thermodynamic data are provided below: H2SO3(aq) H*(aq) HSO3 (aq) HP kcal/mole -145.5 -151.9 S° cal/mole K 56 26 (a) Calculate the value of AG° at 25°C for the ionization reaction. (b) Calculate the value of K at 25°C for the ionization reaction. (c) Account for the signs of AS® and AH° for the ionization reaction in ter and ions present.

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
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Chapter12: Chemical Equilibrium
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Problem 12.67PAE: 12.67 Hydrofluoric acid is a weak acid used in the building industry to etch patterns into glass for...
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6-Consider the first ionization of sulfurous acid:
H2SO3(aq) → H*(aq) + HSO3 (aq)
Certain related thermodynamic data are provided below:
H2SO3(aq)
H* (aq) HSO3 (aq)
-----
Hf kcal/mole
-145.5
-151.9
S° cal/mole K
56
26
(a) Calculate the value of AG° at 25°C for the ionization reaction.
(b) Calculate the value of K at 25°C for the ionization reaction.
(c) Account for the signs of AS° and AH° for the ionization reaction in terms of the molecules
and ions present.
Transcribed Image Text:6-Consider the first ionization of sulfurous acid: H2SO3(aq) → H*(aq) + HSO3 (aq) Certain related thermodynamic data are provided below: H2SO3(aq) H* (aq) HSO3 (aq) ----- Hf kcal/mole -145.5 -151.9 S° cal/mole K 56 26 (a) Calculate the value of AG° at 25°C for the ionization reaction. (b) Calculate the value of K at 25°C for the ionization reaction. (c) Account for the signs of AS° and AH° for the ionization reaction in terms of the molecules and ions present.
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