1. [Biofilter] A biofilter has been chosen for eliminating odour problems around a process plant. The odorous compound is present in an exhaust air with an average flow rate of 12.5 m³/s and concentration of 3810 ppbv. The concentration must be decreased to 500 ppbv to meet the consent standards. The dimensionless Henry's constant for the odorous compound is 0.11 and the reaction coefficient is 0.15 min-1. The degradation reaction follows first-order kinetics. From analysis of other biofilters, it is known that acceptable face velocities are 35-80 m/h. Estimate the range of filter bed heights needed to ensure the consent standards are met. [Ans: 0.87-1.99 m]

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Parameter
ommon parameters used to describe blofilters and their performance
Empty bed residence time
(EBRT)
Volumetric mass loading
[mass/(volume x time)]
(e.g.: g m-³ s-¹)
Removal efficiency (RE or n)
Elimination capacity (EC)
[mass/(volume × time)]
(e.g.: g m-³ s-¹)
Equation
EBRT =
Vf
Qg
Vol mass loading
RE=n=
EC =
=
Cin - Cout
Cin
Qg (Cin-Cout)
Vf
Qg Cin
Vf
Biofiltration
Comments
n = 1 - exp
Allows estimation of filter size for
a given flowrate of waste gas
V₁=filter bed volume
Qg = volumetric flowrate of waste gas
Cin = inlet mass concentration of contaminant
(substance to degrade)
If flow remains constant through a filter, the
mass loading along the length of the filter bed
will decline as contaminant is removed.
Cout= mass concentration of contaminant at
outlet of biofilter
Mass of contaminant degraded per unit
volume of filter material per unit time
EC= volumetric mass loading X RE
The mass transfer of contaminant from the gas to the water phase is generally
not the rate-limiting step, so gas and liquid can be assumed at equilibrium.
Partition between gas and liquid phases is generally described by Henry's law.
11
Assuming a first-order kinetics (valid for low concentrations of pollutant) the
removal efficiency in a biofilter can be given by:
Zk
Кн и
where:
Z = biofilter bed height
KH = Henry's Law constant
u = superficial velocity of the gas (= Q/A, no need to use the porosity of the biofilter bed)
k = empirical reaction term
Transcribed Image Text:Parameter ommon parameters used to describe blofilters and their performance Empty bed residence time (EBRT) Volumetric mass loading [mass/(volume x time)] (e.g.: g m-³ s-¹) Removal efficiency (RE or n) Elimination capacity (EC) [mass/(volume × time)] (e.g.: g m-³ s-¹) Equation EBRT = Vf Qg Vol mass loading RE=n= EC = = Cin - Cout Cin Qg (Cin-Cout) Vf Qg Cin Vf Biofiltration Comments n = 1 - exp Allows estimation of filter size for a given flowrate of waste gas V₁=filter bed volume Qg = volumetric flowrate of waste gas Cin = inlet mass concentration of contaminant (substance to degrade) If flow remains constant through a filter, the mass loading along the length of the filter bed will decline as contaminant is removed. Cout= mass concentration of contaminant at outlet of biofilter Mass of contaminant degraded per unit volume of filter material per unit time EC= volumetric mass loading X RE The mass transfer of contaminant from the gas to the water phase is generally not the rate-limiting step, so gas and liquid can be assumed at equilibrium. Partition between gas and liquid phases is generally described by Henry's law. 11 Assuming a first-order kinetics (valid for low concentrations of pollutant) the removal efficiency in a biofilter can be given by: Zk Кн и where: Z = biofilter bed height KH = Henry's Law constant u = superficial velocity of the gas (= Q/A, no need to use the porosity of the biofilter bed) k = empirical reaction term
1. [Biofilter] A biofilter has been chosen for eliminating odour problems around a process plant. The
odorous compound is present in an exhaust air with an average flow rate of 12.5 m³/s and
concentration of 3810 ppbv. The concentration must be decreased to 500 ppbv to meet the
consent standards. The dimensionless Henry's constant for the odorous compound is 0.11 and
the reaction coefficient is 0.15 min-1. The degradation reaction follows first-order kinetics.
From analysis of other biofilters, it is known that acceptable face velocities are 35-80 m/h.
Estimate the range of filter bed heights needed to ensure the consent standards are met.
[Ans: 0.87-1.99 m]
Transcribed Image Text:1. [Biofilter] A biofilter has been chosen for eliminating odour problems around a process plant. The odorous compound is present in an exhaust air with an average flow rate of 12.5 m³/s and concentration of 3810 ppbv. The concentration must be decreased to 500 ppbv to meet the consent standards. The dimensionless Henry's constant for the odorous compound is 0.11 and the reaction coefficient is 0.15 min-1. The degradation reaction follows first-order kinetics. From analysis of other biofilters, it is known that acceptable face velocities are 35-80 m/h. Estimate the range of filter bed heights needed to ensure the consent standards are met. [Ans: 0.87-1.99 m]
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